"The name is Salsa, Silk Chalk Salsa" - not quite James Bond, but Codenames: Duet is a great game that is perfect for couples or teams.
When you play Castles of Burgundy it is easy to see why the game is so highly rated by so many people. Here is our Castles of Burgundy review.
The X-Files Board Game is a faithful adaptation of the show that does it credit. It semi-cooperative with players playing the FBI and one as the syndicate.